Vitamins & CofactorsApril 18, 20264 min read

Comparison table: B-vitamin deficiencies

Quick-hit shareable content for B-vitamin deficiencies. Include visual/mnemonic device + one-liner explanation. System: Biochemistry.

B-vitamin deficiency questions are some of the most “pattern-recognition heavy” on Step 1/2: you’re expected to match a clinical vignette + a key lab clue to the missing cofactor in seconds. This post is a quick-hit, shareable reference with a comparison table, mnemonic-style hooks, and the highest-yield associations you’ll actually see on exams.


How to use this (fast)

When you get a vignette:

  1. Identify the big syndrome (e.g., dermatitis/diarrhea/dementia, neuropathy, megaloblastic anemia, bleeding).
  2. Look for risk factor (alcohol use, isoniazid, veganism, raw eggs, malabsorption).
  3. Confirm with signature clue (elevated homocysteine, methylmalonic acid, corkscrew hair, pellagra triad).

The “B’s” at a glance: what they do

B vitamins mostly act as enzyme cofactors in energy metabolism and synthesis pathways. Deficiency tends to show up in:

  • High-turnover tissues (bone marrow → anemia)
  • Nervous system (neuropathy, cognitive changes)
  • Skin/GI (dermatitis, diarrhea)

Comparison table: B-vitamin deficiencies (high-yield)

Vitamin (Name)Major cofactor roles (Step-relevant)Classic deficiency findingsOne-liner mnemonic / visual hookHigh-yield risk factors / causesTestable lab clue(s)
B1 (Thiamine)Cofactor for PDH, α-KG dehydrogenase, BCKD, transketolase (PPP)Wernicke-Korsakoff: confusion, ophthalmoplegia, ataxia; memory issues/confabulation. Dry beriberi (peripheral neuropathy), wet beriberi (high-output CHF)“Thiamine powers the brain’s fuel gauge” → low B1 = neuro + heart failureAlcohol use disorder, malnutrition, bariatric surgery, refeeding↓RBC transketolase activity; lactic acidosis can occur (impaired PDH)
B2 (Riboflavin)Precursor to FAD/FMN (redox reactions; ETC)Cheilosis, angular stomatitis, glossitis, corneal vascularization“B2 keeps lips & tongue ‘lit’”Poor diet, malabsorptionNonspecific—think mucocutaneous findings
B3 (Niacin)Precursor to NAD⁺/NADP⁺Pellagra: 3 D’s (Dermatitis, Diarrhea, Dementia) ± death“Niacin = ‘3 D’s’” (picture a sunburned brain with diarrhea)Hartnup disease, carcinoid syndrome (tryptophan shunted to serotonin), alcoholism, malnutrition, isoniazidCan be from ↓tryptophan availability; may coexist with other deficiencies
B5 (Pantothenic acid)Component of CoA and fatty acid synthaseRare; dermatitis, enteritis, alopecia, ± adrenal insufficiency; burning feet syndrome“Pantothenic = ‘Pan’ = in everything” → deficiency is rareSevere malnutritionTypically clinical diagnosis; uncommon on exams
B6 (Pyridoxine)Cofactor for transamination, decarboxylation (neurotransmitters), glycogen phosphorylase, heme synthesis (ALA synthase), cystathionine synthasePeripheral neuropathy, seizures/irritability, cheilosis; sideroblastic anemia“B6 builds blood + brain chemicals”Isoniazid, hydralazine, penicillamine, OCPs, alcoholismMay see ↑homocysteine (due to impaired cystathionine synthase)
B7 (Biotin)Cofactor for carboxylases: pyruvate → OAA, acetyl-CoA → malonyl-CoA, propionyl-CoA → methylmalonyl-CoADermatitis, alopecia, enteritis“Biotin = Beauty vitamin” (hair/skin)Raw egg whites (avidin binds biotin), long-term antibioticsCarboxylase-related issues; classically hair loss + rash
B9 (Folate)THF for 1-carbon transfers (DNA/RNA synthesis); homocysteine → methionine (with B12)Megaloblastic anemia, glossitis; neural tube defects in fetus“Folate = Fetal neural tube + Fast-dividing cells”Poor diet, alcoholism; methotrexate, TMP-SMX, phenytoin; pregnancy↑Homocysteine, normal methylmalonic acid
B12 (Cobalamin)Cofactor for methionine synthase and methylmalonyl-CoA mutaseMegaloblastic anemia + neurologic deficits (subacute combined degeneration: dorsal columns/corticospinal tracts)“B12 = Brain + Bone marrow”Pernicious anemia (anti–intrinsic factor), ileal disease/resection (Crohn), Diphyllobothrium latum, veganism↑Homocysteine + ↑Methylmalonic acid; can see hypersegmented neutrophils

The ultra-high-yield discriminator: folate vs B12

If the question is basically “megaloblastic anemia—now pick the vitamin,” your fastest move is:

FeatureFolate (B9)B12 (Cobalamin)
Neuro symptomsNoYes (posterior column + corticospinal signs)
Homocysteine
Methylmalonic acidNormal
Common causePoor diet, alcohol, MTX/TMPPernicious anemia, ileal disease, veganism

Exam trap: Giving folate can improve anemia in B12 deficiency but does not fix neurologic injury.


Rapid-fire “visual hooks” you can recall under time pressure

B1 (Thiamine): “4 enzymes + 2 syndromes”

  • Enzymes: PDH, α-KG DH, BCKD, transketolase
  • Syndromes: Wernicke-Korsakoff, beriberi
  • Vignette feel: alcohol use + confusion/ataxia/ophthalmoplegia → give thiamine before glucose.

B3 (Niacin): “Pellagra poster”

Imagine a sun-exposed rash in a collar pattern (Casal necklace) + diarrhea + confusion.

  • Think: carcinoid (tryptophan diverted) or Hartnup (can’t absorb neutral AAs).

B6 (Pyridoxine): “Isoniazid steals B6”

  • INH → functional B6 deficiency → neuropathy + sideroblastic anemia (impaired heme synthesis).
  • USMLE loves “TB treatment + tingling hands” → give pyridoxine.

B7 (Biotin): “Raw eggs wreck hair”

  • Raw egg whites (avidin) bind biotin → alopecia + dermatitis.

B9/B12: “Homocysteine is not enough”

  • Both raise homocysteine; only B12 raises methylmalonic acid and causes neuro deficits.

Quick clinical associations (Step-style)

  • Alcohol use disorder → think B1, B9, ± B6
  • Bariatric surgery / malabsorption → B1 early, B12 later
  • IsoniazidB6
  • Vegan + neuropathyB12
  • Pregnancy + no prenatal vitaminsB9 (neural tube defects)

10-second self-quiz (to cement patterns)

  1. Confusion + ophthalmoplegia + ataxia in an alcoholic → B1 deficiency
  2. Dermatitis + diarrhea + dementia → B3 deficiency
  3. Isoniazid user with neuropathy + microcytic anemia with ring sideroblasts → B6 deficiency
  4. Megaloblastic anemia + ↑methylmalonic acid + paresthesias → B12 deficiency
  5. Megaloblastic anemia + normal methylmalonic acid in pregnancy → B9 deficiency
  6. Alopecia + dermatitis in someone who drinks raw eggs → B7 deficiency